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A 2.5 L flask is filled with 0.25 atm SO3,0.20 atm SO2,and 0.40 atm O2,and allowed to reach equilibrium.Assume the temperature of the mixture is chosen so that Kp = 0.12.Predict the effect on the partial pressure of SO3 as equilibrium is achieved by using Q,the reaction quotient. 2 SO3(g) ⇌ 2 SO2(g) + O2(g)


A) The partial pressure of SO3 will decrease because Q > K.
B) The partial pressure of SO3 will decrease because Q < K.
C) The partial pressure of SO3 will increase because Q < K.
D) The partial pressure of SO3 will increase because Q > K.
E) The partial pressure of SO3 will remain the same because Q = K.

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Use the equilibrium constants for the following reactions at 700°C 2SO2(g) +O2(g) 2SO3(g) 2NO(g) +O2(g) 2NO2(g) K1=4.8K2=16\begin{array}{l}\begin{array}{lll}2 \mathrm{SO}_{2}(g) +\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) \\2 \mathrm{NO}(g) +\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g) \\\end{array}\begin{array}{lll}K_{1}=4.8 \\K_{2}=16\end{array}\end{array} To determine the equilibrium constant for the following reaction. SO3(g) + NO(g) ⇌ SO2(g) + NO2(g)


A) 0.30
B) 0.55
C) 0.85
D) 1.8
E) 3.3

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At a given temperature,the equilibrium constant (Kp) for the decomposition of dinitrogen tetraoxide to nitrogen dioxide is 0.172.If 0.224 atm N2O4 is sealed in a flask,what partial pressure of NO2 will exist at equilibrium? N2O4(g) ⇌ 2NO2(g)


A) 0.0385 atm
B) 0.158 atm
C) 0.196 atm
D) 0.257 atm
E) 0.379 atm

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Use the equilibrium constants for the following reactions 2NO(g) N2(g) +O2(g) K1=2.4×10302NO(g) +O2(g) 2NO2(g) K2=2.4×1012\begin{array}{ll}2 \mathrm{NO}(g) \rightleftharpoons \mathrm{N}_{2}(g) +\mathrm{O}_{2}(g) & K_{1}=2.4 \times 10^{30} \\2 \mathrm{NO}(g) +\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g) & K_{2}=2.4 \times 10^{12}\end{array} To determine the equilibrium constant for the reaction below. N2(g) + 2O2(g) ⇌ 2NO2(g)


A) 1.7 × 10−43
B) 1.0 × 10−18
C) 5.8 × 1018
D) 2.4 × 1030
E) 5.8 × 1042

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The value of the equilibrium constant for the following reaction is 345. A + 2B ⇌ 3C + D What is the value of the equilibrium constant for the reaction below? 2A + 4B ⇌ 6C + 2D


A) K = 345
B) K = (345) 2 = 1.19 × 105
C) K = (345) 1/2 = 18.6
D) K = (2 × 345) 2 = 4.76 × 105
E) K = 2 × (345) 2 = 2.38 × 105

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Nitrogen can react with oxygen to form nitrogen monoxide. N2( g) +O2( g) 2NO(g) \mathrm{N}_{2}(\mathrm{~g}) +\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g}) \quad \quad \quad K=1.0×1030 at 25CK=1.0 \times 10^{30} \text { at } 25^{\circ} \mathrm{C} When equilibrium is established,the partial pressures of nitrogen and oxygen are 1.2 atm and 3.1 atm,respectively.What is the equilibrium pressure of nitrogen monoxide?


A) 3.7 × 10−30 atm
B) 1.9 × 10−15 atm
C) 2.7 × 10−13 atm
D) 1.9 × 10−10 atm
E) 3.7 × 10−7 atm

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Which of the following reactions is a heterogeneous equilibrium expression?


A) 2NO(g) + O2(g) ⇌ 2NO2(g)
B) 2NH3(g) ⇌ N2(g) + 3H2(g)
C) 2H2(g) + O2(g) ⇌ 2H2O(g)
D) 2S(s) + 3O2(g) ⇌ 2SO3(g)
E) C2H4(g) + H2(g) ⇌ C2H6(g)

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For which of the following reactions does Kc equal Kp?


A) Sn(s) + 2H2O(g) ⇌ SnO2(s) + 2H2(g)
B) 2C2H6(g) + 7O2(g) ⇌ 4CO2(g) + 6H2O(g)
C) NH4Cl(s) ⇌ NH3(g) + HCl(g)
D) N2(g) + 3H2(g) ⇌ 2NH3(g)
E) CaCO3(s) ⇌ CaO(s) + CO2(g)

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If the value of Q is less than Kp,then


A) the system is in equilibrium.
B) a catalyst is necessary to achieve equilibrium.
C) the reaction will go left or right depending upon the reaction stoichiometry.
D) the reaction will proceed to the right until equilibrium is established.
E) the reaction will proceed to the left until equilibrium is established.

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