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The molar masses of helium and oxygen are 4.0 g/mol and 16 g/mol,respectively.At the same temperature and pressure,1 mole of helium will occupy


A) the same volume as 1 mole of oxygen.
B) four times the volume of 1 mole of oxygen.
C) twice the volume of 1 mole of oxygen.
D) half the volume of 1 mole of oxygen.
E) one-fourth the volume of 1 mole of oxygen.

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A sample of carbon dioxide is collected over water at 25°C (vapor pressure H2O(l) = 23.8 mm Hg) .The CO2 and water vapor occupy a volume of 1.80 L at a pressure of 783.0 mm Hg.What mass of CO2 is present?


A) 3.23 g
B) 4.40 g
C) 9.02 g
D) 14.7 g
E) 16.3 g

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If the volume of a confined gas is expanded to four times the original volume while its temperature remains constant,what change will be observed?


A) The pressure of the gas will decrease to 1/4 of its original value.
B) The pressure of the gas will decrease to 1/2 of its original value.
C) The pressure of the gas will remain unchanged.
D) The pressure of the gas will increase to twice its original value.
E) The pressure of the gas will increase to four times its original value.

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What volume does 22.4 moles of hydrogen gas occupy at 0°C and 1.00 atm?


A) 0.0821 L
B) 1.00 L
C) 22.4 L
D) 184 L
E) 502 L

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Water can be decomposed by electrolysis to hydrogen gas and oxygen gas.If 2.33 g of water is decomposed to H2(g) and O2(g) and the gases are collected in a 1.00 L flask over water at 25°C (vapor pressure H2O(l) = 23.8 mm Hg) ,what is the pressure in the flask?


A) 3.19 atm
B) 4.71 atm
C) 4.75 atm
D) 4.78 atm
E) 9.52 atm

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Methane gas,CH4,effuses through a barrier at a rate of 0.568 mL/minute.If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute,what is the molar mass of the gas?


A) 20.8 g/mol
B) 28.0 g/mol
C) 32.0 g/mol
D) 43.9 g/mol
E) 64.0 g/mol

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A balloon is filled with He gas to a volume of 2.10 L at 35°C.The balloon is placed in liquid nitrogen until its temperature reaches -196°C.Assuming the pressure remains constant,what is the volume of the cooled balloon?


A) −0.375 L
B) 0.375 L
C) 0.525 L
D) 0.00909 L
E) 8.40 L

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At 338 mm Hg and 72°C,a sample of carbon monoxide gas occupies a volume of 0.225 L.The gas is transferred to a 1.50-L flask and the temperature is reduced to -15°C.What is the pressure of the gas in the flask?


A) 8.91 mm Hg
B) 37.9 mm Hg
C) 67.8 mm Hg
D) 3.018 × 103 mm Hg
E) 5.48 × 104 mm Hg

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An unknown gas contains 85.6% C and 14.4% H.At 0.455 atm and 425 K,the gas has a density of 0.549 g/L.What is the molecular formula of the gas?


A) CH4
B) C2H4
C) C3H6
D) C4H6
E) C4H8

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In an experiment,argon is allowed to effuse through a tiny opening into an evacuated 5.00 × 102 mL flask for 30.0 seconds,at which point the pressure in the flask is found to be 15.0 mm Hg.The experiment is repeated using an unknown gas at the same temperature and pressure.After 30.0 seconds,the pressure is found to be 47.4 mm Hg.What is the molar mass of the gas?


A) 4.00 g/mol
B) 16.0 g/mol
C) 28.0 g/mol
D) 32.0 g/mol
E) 83.8 g/mol

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A

A volatile compound with a mass of 0.8822 grams is placed in an evacuated 0.250 L flask.The flask is heated to evaporate the compound.At 99°C,the pressure in the flask is 1.25 atm.What is the molar mass of the compound?


A) 86.2 g/mol
B) 116 g/mol
C) 229 g/mol
D) 257 g/mol
E) 303 g/mol

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At 1.00 km above sea level,the atmospheric pressure is 675 mm Hg and the temperature is 282 K.If nitrogen comprises 78.1% (mole percent) of air,what is the density of nitrogen at this height?


A) 0.0238 g/L
B) 0.521 g/L
C) 0.839 g/L
D) 1.07 g/L
E) 638 g/L

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Calculate the density (in g/L) of CH4(g) at 75°C and 2.1 atm.(R = 0.08206 L · atm/mol · K)


A) 0.18 g/L
B) 0.85 g/L
C) 1.2 g/L
D) 3.2 g/L
E) 5.5 g/L

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At 21°C,a gas cylinder containing nitrogen has an internal volume and pressure of 46.6 L and 1.50 × 102 atm.What mass of nitrogen gas is contained in the cylinder?


A) 2.90 × 102 g
B) 4.05 × 103 g
C) 8.11 × 103 g
D) 1.14 × 105 g
E) none of the above

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A balloon is filled with 1.50 L of helium gas at sea level,1.00 atm and 32°C.The balloon is released and it rises to an altitude of 30,000 ft.If the pressure at this altitude is 228 mm Hg and the temperature is −45°C,what is the volume of the balloon?


A) 0.336 L
B) 1.56 L
C) 1.68 L
D) 2.81 L
E) 3.74 L

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Place the following units of pressure in order from lowest to highest pressure.


A) 1 atm < 1 Pa < 1 mm Hg < 1 bar
B) 1 mm Hg < 1 bar < 1 atm < 1 Pa
C) 1 Pa < 1 mm Hg < 1 bar < 1 atm
D) 1 Pa < 1 mm Hg < 1 atm < 1 bar
E) 1 bar < 1 mm Hg < 1 Pa < 1 atm

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A tightly sealed 4.0-L flask contains 884 mm Hg of N2 at 94.0°C.The flask is cooled until the pressure is reduced to 442 mm Hg.What is the temperature of the gas?


A) -47.0°C
B) 47.0°C
C) -89.5°C
D) 184°C
E) 188°C

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C

A volume of 3.0 L of butane is burned in excess oxygen.Balance the chemical equation below and determine how many total liters of gases are produced.Assume that both the reactant and product temperature is 500 K and the pressure of the system remains constant at 1.0 atm. C4H10(g) + O2(g) → CO2(g) + H2O(g)


A) 3.0 L
B) 6.0 L
C) 12 L
D) 27 L
E) 42 L

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Water can be decomposed by electrolysis to hydrogen gas and oxygen gas.What mass of water must decompose to yield 24.0 L of oxygen gas at 1.00 atm and 25°C? 2H2O(l) → 2H2(g) + O2(g)


A) 11.1 g
B) 17.7 g
C) 23.6 g
D) 35.3 g
E) 70.7 g

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Avogadro's law states that


A) 1 liter of any gas contains 6.02 × 1023 gas molecules.
B) the volume of a gas is directly proportional to its temperature.
C) the gas constant equals 0.0821 L · atm/(mol · K) for all ideal gases.
D) the volume of a gas must always be a constant.
E) equal volumes of all gases at the same pressure and temperature contain an equal number of moles.

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E

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