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In forming ions of the first series of transition metals, the 4s electrons are lost before the 3d electrons.

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Which of the following elements has the smallest atomic radius?


A) Li
B) Ne
C) Rb
D) Sr
E) Xe

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Metallic behavior is generally associated with


A) elements with very negative electron affinities.
B) elements with low ionization energies.
C) elements with small atomic radii.
D) elements with unpaired electrons.
E) elements with partially filled p orbitals.

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The most basic oxides are formed from elements found in the __________________ region of the periodic table.


A) upper right
B) upper left
C) center
D) lower right
E) lower left

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In the ground state of an atom of silver (Ag) , how many electrons will there be with the quantum number l = 1? (The n, ml and ms quantum numbers may have any appropriate values.)


A) 9
B) 12
C) 18
D) 24
E) 36

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Which of the following elements will form a cation with a +2 charge?


A) Si
B) Sr
C) Ga
D) Cs
E) S

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Elements with _______________ first ionization energies and ___________ electron affinities generally form anions.


A) low, very negative
B) high, positive or slightly negative
C) low, positive or slightly negative
D) high, very negative
E) None of these choices is generally correct.

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of potassium, K.


A) 4, 1, -1, ½
B) 4, 1, 0, ½
C) 4, 0, 1, ½
D) 4, 0, 0, ½
E) 4, 1, 1, ½

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Describe how the atomic radii of main group elements vary with position in the periodic table.

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Among the main group elements,...

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Which of the following ions will be most likely to form when selenium ionizes?


A) Se6+
B) Se4+
C) Se2+
D) Se
E) Se

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The effective nuclear charge for an atom is less than the actual nuclear charge due to


A) shielding.
B) penetration.
C) paramagnetism.
D) electron-pair repulsion.
E) relativity.

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Which of the following elements is paramagnetic?


A) Kr
B) Zn
C) Sr
D) V
E) Ar

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Electron affinities become increasingly positive toward the right hand end of a period.

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When comparing the successive ionization energies of an element, an unusually big increase in ionization energy is seen when


A) the first valence electron is removed.
B) the second valence electron is removed.
C) the eighth electron of is removed.
D) the first core electron is removed.
E) the last valence electron is removed.

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Elements with the highest first ionization energies are found in the ___________ region of the periodic table.


A) lower left
B) upper left
C) center
D) lower right
E) upper right

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An atom of element number 33 (As) is in its ground electronic state. Which one of the following sets quantum numbers could not apply to any of its electrons?


A) n = 2; l = 1; ml = -1; ms = +½
B) n = 3; l = 0; ml = 0 ; ms = -½
C) n = 3; l = 2; ml = -2; ms = -½
D) n = 4; l = 0; ml = 0 ; ms = -½
E) n = 4; l = 2; ml = 1 ; ms = +½

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Select the correct electron configuration for Cu (Z = 29) .


A) [Ar]4s23d9
B) [Ar]4s13d10
C) [Ar]4s24p63d3
D) [Ar]4s24d9
E) [Ar]5s24d9

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In many-electron atoms, which quantum numbers specify the energy of an electron?


A) n and l
B) n and ml
C) l and ml
D) n and ms
E) n, l and ml

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Select the diamagnetic ion.


A) Cu2+
B) Ni2+
C) Cr3+
D) Sc3+
E) Cr2+

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"Each electron in an atom must have its own unique set of quantum numbers" is a statement of


A) the aufbau principle.
B) the Pauli exclusion principle.
C) Hund's rule.
D) the periodic law.
E) Heisenberg's principle.

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