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Does a precipitate of magnesium fluoride form if 300.0 mL of 1.1 × 10-3 M MgCl2 are added to 500.0 mL of 1.2 × 10-3 M NaF? [Ksp(MgF2) = 6.9 × 10-9]


A) Yes, because Q > Ksp.
B) No, because Q < Ksp.
C) No, because Q = Ksp.
D) Yes, because Q < Ksp.
E) No, because Q > Ksp.

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The pH of a solution that is 0.20 M CH3COOH and 0.20 M CH3COONa should be higher than the pH of a 0.20 M CH3COOH solution.

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Propanoic acid (CH3CH2COOH) has a Ka of 1.34 × 10-5. A 25.00-mL sample of 0.1000 mol • L-1 propanoic acid (in flask) is titrated with 0.1000 mol • L-1 NaOH solution, added from a buret. Carry out the calculations of the quantities indicated below. a. The pH after 0.00 mL of NaOH is added. b. The pH after 15.00 mL of NaOH is added.

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Which cation would form an insoluble chloride when reacted with HCl?


A) Na+
B) Ag+
C) B3+
D) Ca2+
E) Cs+

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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 × 10-10) solution.


A) 5.15
B) 8.71
C) 5.85
D) 9.91
E) 13.0

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Which of the following is correct for the equivalence point in an acid-base titration?


A) The pH is at its highest value for any reaction.
B) The amounts of acid and base combined are in a stoichiometric ratio at the equivalence point in an acid-base titration.
C) The pH is 7.0.
D) The pH is equal to the pKa of the weak acid.
E) The pH is equal to the pKb of the weak base.

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Which pair of substances cannot form a buffered aqueous solution?


A) HCN and KCN
B) NH3 and (NH4) 2SO4
C) HNO3 and NaNO3
D) HF and NaF
E) HNO2 and NaNO2

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What is the name of the principle of selective precipitation used to identify the types of ions present in a solution?


A) Ionization
B) Selective ion precipitation
C) Selective ion typing
D) Limited precipitation
E) Qualitative analysis

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________ is the way to identify the types of ions in a solution using selective precipitation.

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Qualitativ...

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40.0 ml of an acetic acid solution of unknown concentration is titrated with 0.100 M NaOH. After 20.0 mL of the base solution has been added, the pH in the titration flask is 5.10. What was the concentration of the original acetic acid solution? (Ka(CH3COOH) = 1.8 × 10-5)


A) 0.11 M
B) 0.022 M
C) 0.072 M
D) 0.050 M
E) 0.015 M

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Increasing the concentrations of the components of a buffer solution will increase the buffer range.

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Which is included in the Ksp expression? I. Concentration of cation II) Concentration of anion III) Concentration of solid


A) I only
B) II only
C) III only
D) I and II
E) I, II and III

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The solubility of lead(II) chloride is 0.45 g/100 mL of solution. What is the Ksp of PbCl2?


A) 4.9 × 10-2
B) 1.7 × 10-5
C) 8.5 × 10-6
D) 4.2 × 10-6
E) 2.6 × 10-4

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Which best describes the pH at the equivalence point of a titration of a weak acid with a strong base?


A) Less than zero
B) Between 0 and 7
C) Close to 7.0
D) Between 7 and 14
E) Greater than 14

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If 50.0 mL of 1.2 × 10-3 M Pb(NO3) 2 are added to 50.0 mL of 2.0 × 10-4 M Na2S, what takes place?


A) A precipitate of PbS forms.
B) A precipitate of NaNO3 forms.
C) A precipitate of Na2S forms.
D) A precipitate of Pb(NO3) 2 forms.
E) No precipitate forms.

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A solution is prepared by mixing 50.0 mL of 0.50 M Cu(NO3) 2 with 50.0 mL of 0.50 M Co(NO3) 2. Sodium hydroxide is slowly added to the mixture. Which precipitates first? [Ksp(Cu(OH) 2) = 2.2 × 10-20, Ksp(Co(OH) 2) = 1.3 × 10-15]


A) Co(OH) 2
B) Co(NO3) 2
C) Cu(NO3) 2
D) Cu(OH) 2
E) No precipitate is formed.

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What is the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO) and 0.80 mole of sodium cyanate (NaCNO) in enough water to make 1.0 liter of solution? [Ka(HCNO) = 2.0 × 10-4]


A) 0.97
B) 3.10
C) 4.40
D) 3.70
E) 4.30

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What is the pH of a buffer that consists of 0.20 M NaH2PO4 and 0.40 M Na2HPO4? [Ka(NaH2PO4) = 6.2 × 10-8]


A) 6.51
B) 6.91
C) 7.51
D) 7.90
E) 8.13

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What is the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl? [Ka(HOCl) = 3.2 × 10-8]


A) 0.39
B) 3.94
C) 6.58
D) 7.49
E) 8.40

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When a strong acid is titrated with a weak base, the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is equal to the pKa of the conjugate acid.
E) is equal to the pKb of the base.

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