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The covalent bond with the greatest polarity would form in which of the atom pairs below?


A) Br - Br
B) S - O
C) C - P
D) C - O
E) B - O

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Which one of the following is most likely to be a covalent compound?


A) KF
B) CaCl2
C) SF4
D) Al2O3
E) CaSO4

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Use bond energies to estimate the enthalpy change for the reaction of one mole of CH4 with chlorine gas to give CH3Cl and hydrogen chloride. BE(C-H) = 414 kJ/mol BE(C-Cl) = 326 kJ/mol BE(H-Cl) = 432 kJ/mol BE(Cl-Cl) = 243 kJ/mol


A) -101 kJ/mol
B) -106 kJ/mol
C) +331 kJ/mol
D) +106 kJ/mol
E) +101 kJ/mol

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The Lewis dot symbol for the calcium ion is


A) The Lewis dot symbol for the calcium ion is A)    <sup>2+</sup> B) (-Ca-)  C)    <sup>2+</sup> D) Ca<sup>2+</sup> E) Ca 2+
B) (-Ca-)
C) The Lewis dot symbol for the calcium ion is A)    <sup>2+</sup> B) (-Ca-)  C)    <sup>2+</sup> D) Ca<sup>2+</sup> E) Ca 2+
D) Ca2+
E) Ca

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What is total number of lone pairs in the best Lewis structure for SOF4 that exceeds the octet rule (S is the central atom) ?


A) 0
B) 2
C) 14
D) 16
E) 18

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A polar covalent bond would form in which one of the following pairs of atoms?


A) Cl - Cl
B) Si - Si
C) Ca - Cl
D) Cr - Br
E) P - Cl

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Which one of the following is most likely to be a covalent compound?


A) Rb2O
B) BaO
C) SrO
D) SeO2
E) MnO2

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The formal charge on the sulfur atom in the resonance structure of sulfur dioxide which has one single bond and one double bond is


A) 0.
B) +1.
C) -1.
D) +2.
E) -2.

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Which of the following solids would have the lowest melting point?


A) KI
B) KBr
C) KCl
D) KF

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What is the formal charge on the singly bonded oxygens in the Lewis structure for the carbonate ion?


A) -2
B) -1
C) 0
D) +1
E) +2

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The bond in which of the following pairs of atoms would be the least polar (i.e., lowest percent ionic character) ?


A) C - Cl
B) C - C
C) C - H
D) O - C
E) N - C

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B

Write the Lewis structure for the product that forms when boron trifluoride combines with ammonia.

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What is the formal charge on sulfur in the best Lewis structure for the SCN- (thiocyanate) ion?


A) +2
B) -2
C) +1
D) -1
E) 0

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Write a Lewis structure for the phosphate ion, PO43-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for PO43- that obey the octet rule.

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Use bond energies to estimate the enthalpy of formation of HBr(g) . BE(H-H) = 436 kJ/mol BE(Br-Br) = 192 kJ/mol BE(H-Br) = 366 kJ/mol


A) +262 kJ/mol
B) -52 kJ/mol
C) -104 kJ/mol
D) +104 kJ/mol
E) +52 kJ/mol

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B

Which of the following ionic solids would have the largest lattice energy?


A) KF
B) KI
C) LiF
D) LiI
E) NaF

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What type of chemical bond holds the atoms together within a water molecule?


A) Ionic bond
B) Nonpolar covalent bond
C) Polar covalent bond
D) Coordinate covalent bond

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Write a Lewis structure for the chlorite ion, ClO2-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Write a Lewis structure for SO3 that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Which of the following solids would have the highest melting point?


A) NaF
B) NaCl
C) NaBr
D) NaI

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