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In which of the following aqueous solutions does the weak acid exhibit the highest percentage ionization?


A) 0.01 M H2SO3 (Ka = 1.4 × 10-2)
B) 0.01 M HCN (Ka = 6.2 × 10-10)
C) 0.01 M H2CO3 (Ka = 4.5 × 10-7)
D) 0.01 M HC3H5O2 (Ka = 1.3 × 10-5)
E) 0.01 M HOCl (Ka = 3.5 × 10-8)

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A Lewis acid is an electron-pair acceptor, and a Lewis base is an electron-pair donor.

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Ka for HF is 7.0 × 10-4. Kb for the fluoride ion is ________.


A) 2.0 × 10-8
B) 1.4 × 10-11
C) 7.0 × 10-18
D) 7.0 × 10-4
E) 1.4 × 103

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Which one of the following is a Br∅nsted-Lowry base?


A) (CH3) 3N
B) CH3COOH
C) HF
D) HNO2
E) none of the above

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A solution of formic acid is 3.0% dissociated at 25.0 °C. What is the original concentration (in M)of the formic acid solution? The Ka at 25.0 °C for formic acid is 1.8 × 10-4.

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What is the pH of an aqueous solution at 25.0 °C in which [OH-] is 0.0030 M?


A) 5.81
B) -11.48
C) 2.52
D) -2.52
E) 11.48

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Using the data in the table, which of the conjugate acids below is the weakest acid? Using the data in the table, which of the conjugate acids below is the weakest acid?   A) NH<sub>4</sub><sup>+</sup> B) C<sub>5</sub>H<sub>5</sub>NH<sup>+</sup> C) H<sub>3</sub>NOH<sup>+</sup> D) NH<sub>3</sub>CH<sub>3</sub><sup>+</sup> E) NH<sub>4</sub><sup>+</sup> and NH<sub>3</sub>CH<sub>3</sub><sup>+</sup>


A) NH4+
B) C5H5NH+
C) H3NOH+
D) NH3CH3+
E) NH4+ and NH3CH3+

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What is the concentration (in M) of hydronium ions in a solution at 25.0 °C with pH = 4.146?


A) 4.15
B) 9.85
C) 1.40 × 10-10
D) 7.15 × 10-5
E) none of the above

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Which of the following acids will be the strongest?


A) H2SO4
B) HSO4-
C) H2SO3
D) H2SeO4
E) HSO3-

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The molar concentration of hydroxide ion in pure water at 25 °C is ________.


A) 1.00
B) 0.00
C) 1.0 × 10-14
D) 1.0 × 10-7
E) 7.00

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Using the data in the table, which of the conjugate bases below is the strongest base? Using the data in the table, which of the conjugate bases below is the strongest base?   A) OAc<sup>-</sup> B) C<sub>7</sub>H<sub>5</sub>O<sub>2</sub><sup>-</sup> C) NO<sub>2</sub><sup>-</sup> D) F<sup>-</sup> E) OAc- and C<sub>7</sub>H<sub>5</sub>O<sub>2</sub><sup>-</sup>


A) OAc-
B) C7H5O2-
C) NO2-
D) F-
E) OAc- and C7H5O2-

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A Br∅nsted-Lowry acid is defined as a substance that ________.


A) increases Ka when placed in H2O
B) decreases [H+] when placed in H2O
C) increases [OH-] when placed in H2O
D) acts as a proton acceptor
E) acts as a proton donor

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In acidic solution, ________.


A) [H3O+] > [OH-]
B) [H3O+] = [OH-]
C) [H3O+] < [OH-]
D) [OH-] > 7.00
E) [H3O+] = 0M

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Which one of the following is a Br∅nsted-Lowry acid?


A) (CH3) 3NH+
B) CH3COOH
C) HF
D) HNO2
E) all of the above

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The Ka of hypochlorous acid (HClO) is 3.00 × 10-8. What is the pH at 25.0 °C of an aqueous solution that is 0.0200 M in HClO?


A) +2.45
B) -2.45
C) -9.22
D) +9.22
E) +4.61

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What is the pH of an aqueous solution at 25.0 °C that contains 3.98 × 10-9 M hydroxide ion?


A) 8.40
B) 5.60
C) 9.00
D) 3.98
E) 7.00

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Classify the following compounds as weak bases (W) or strong bases (S) : methylamine carbonate ion potassium hydroxide


A) W W S
B) S S S
C) S W W
D) W S S
E) W S W

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Calculate the pH of 0.726 M anilinium hydrochloride (C6H5NH3Cl) solution in water, given that Kb for aniline is 3.83 × 10-4.


A) 1.78
B) 12.22
C) 5.36
D) 8.64
E) 12.42

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The Ka for formic acid (HCO2H) is 1.8 × 10-4. What is the pH of a 0.20 M aqueous solution of sodium formate (NaHCO2) ?


A) 11.64
B) 5.48
C) 3.39
D) 8.52
E) 4.26

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Which solution below has the highest concentration of hydronium ions?


A) pH = 3.0
B) pH = 10
C) pH = 7.0
D) pH = 6.4
E) pH = 11.2

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