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Exam 8: Haloalkanes, Halogenation, and Radical Reactions

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Question 21

Multiple Choice

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Which of the following alkanes does not undergo monobromination to form a single bromoalkane as the major product?

A) 1
B) 2
C) 3
D) 4

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Question 22

Multiple Choice

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What is the IUPAC name of the following compound?

A) (R) -1-chloro-3-methyl-2-cyclohexene
B) (S) -1-chloro-3-methyl-2-cyclohexene
C) (R) -3-chloro-1-methylcyclohexene
D) (S) -3-chloro-1-methylcyclohexene

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Question 23

Multiple Choice

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Which halogen is most useful in the regioselective radical halogenation of alkenes??

What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

What is the major product obtained from the reaction of 2-methyl-2-butene with hydrogen bromide in the presence of peroxides?

Consider the following reaction. In the absence of peroxides, the major product of the reaction is shown below.

What are the major organic products obtained from the following reaction?

What is the major organic product obtained from the following reaction?

Provide the IUPAC name of the following compound (shown as a Fischer projection).

Which of the following has the list of compounds in the correct order of decreasing molecular polar (more polar > less polar) ?

What is the reactive intermediate in the autooxidation of cyclohexene?

What type of reactive intermediate is formed upon irradiation of a solution of toluene (Ph-CH₃) and bromine?

What is the structure of all of the monobrominated products, including regioismers and stereoisomers, obtained from the following reaction?

Which of the following statements is not true about the allyl radical

The products of the addition of HBr to an alkene in the presence of peroxides is accounted for by a polar reaction mechanism.

The number of possible monobromination products of cyclopentane is______.

During bromination using NBS, the concentration of bromine remains ________throughout the course of the reaction.

Provide the IUPAC name of the following compound (shown as a Fischer projection).