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The standard emf for the cell using the overall cell reaction below is +0.48 V: \quad\quad Zn(s) + Ni2+\mathrm { Ni } ^ { 2 + } (aq) ? Zn2+\mathrm { Zn } ^ { 2 + } (aq) + Ni(s) The emf generated by the cell when [ Ni2+\mathrm { Ni } ^ { 2 + } ] = 6.50 mol L-1 and [ Zn2+\mathrm { Zn } ^ { 2 + } ] = 0.500 mol L-1 is --------  V. \text { V. }


A) 0.55
B) 0.45
C) 0.61
D) 0.50
E) 0.51

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Which of the following is the strongest oxidizing agent?


A) Br2(l)
B) Au3+(aq)
C) Ag(s)
D) Br- (aq)
E) Au(s)

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °C: \quad\quad\quad Sn(s) | Sn2+(aq,0.022 mol L-1) \| Ag+(aq,2.7 mol L-1) | Ag(s) E°(Sn2+/Sn) = -0.14 V and E°(Ag+/Ag) = +0.80 V


A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V

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What is undergoing reduction in the redox reaction represented by the following cell notation? \quad\quad\quad Fe(s) | Fe3+(aq) \| Cl2(g) | Cl- (aq) | Pt(s)


A) Fe(s)
B) Fe3+(aq)
C) Cl2(g)
D) Cl- (aq)
E) Pt(s)

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Determine which of the following pairs of reactants will result in a spontaneous reaction at 25 °C.


A) Pb2+(aq) + Cu(s) ; if E°(Pb2+/Pb) = -0.13V and E°(Cu2+/Cu) = +0.16V
B) Ag+(aq) + Br- (aq) ; if E°(Ag+/Ag) = 0.80V and E°(Br2/Br-) = +1.09V
C) Li+(aq) + Al(s) ; if E°(Li+/Li) = -3.04V and E°(Al3+/Al) = -1.66V
D) Fe3+(aq) + Ni(s) ; if E°(Fe3+/Fe) = -0.04V and E°(Ni2+/Ni) = -0.23V
E) Cd2+(aq) + I-(aq) ; if E°(Cd2+/Cd) = -0.40V and E°(I2/I-) = + 0.54V

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Consider the following standard reduction potentials: \quad\quad Ni2+(aq) + 2 e- → Ni(s) E° = -0.26 V \quad\quad I2(s) + 2 e- → 2 I-(aq) E° = +0.54 V Under standard conditions,


A) Ni2+(aq) is a stronger oxidizing agent than I2(s) ,and I-(aq) is a stronger reducing agent than Ni(s) .
B) I2(s) is a stronger oxidizing agent than Ni2+(aq) ,and Ni(s) is a stronger reducing agent than I-(aq) .
C) Ni(s) is a stronger oxidizing agent than I-(aq) ,and Ni2+(aq) is a stronger reducing agent than I2(s) .
D) I-(aq) is a stronger oxidizing agent than Ni(s) ,and I2(s) is a stronger reducing agent than Ni2+(aq) .

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For the galvanic cell reaction,expressed below using shorthand notation,what half-reaction occurs at the cathode? \quad\quad Zn(s) | Zn2+(aq) || Ni2+(aq) | Ni(s)


A) Zn(s) → Zn2+(aq) + 2 e-
B) Zn2+(aq) + 2 e- → Zn(s)
C) Ni(s) → Ni2+(aq) + 2 e-
D) Ni2+(aq) + 2 e- → Ni(s)

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