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Which of the following is true about the activation energy?


A) It may increase by decreasing the temperature.
B) It may decrease by decreasing the temperature.
C) It may increase by increasing the concentration of reactants.
D) It is practically independent of both temperature and concentration of reactants.

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Given the reaction, 2A + B2 → 2AB, which of the following factors could increase the reaction rate? I. decreasing the temperature II.adding a catalyst III.increasing the surface area of solid reactants


A) I and II
B) II and III
C) I and III
D) II And III
E) III only

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If the kinetic energy of the reactant molecules is not high enough to overcome the activation energy barrier, ________.


A) the reverse reaction will occur
B) no reaction takes place
C) the reaction will occur anyway
D) the products will form at a slower rate

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B

Which of the following is an endothermic reaction?


A) melting ice
B) freezing water
C) sublimation of dry ice
D) condensing water vapor

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A

  -In the diagram above, the containers shown (Box A and BoxB) contain exactly the same number of reactant molecules and are at the same temperature. In which box will the rate of reaction be faster? A) Box A B) Box B C) Rate is about the same in each box. D) No way to tell which is faster from this picture. -In the diagram above, the containers shown (Box A and BoxB) contain exactly the same number of reactant molecules and are at the same temperature. In which box will the rate of reaction be faster?


A) Box A
B) Box B
C) Rate is about the same in each box.
D) No way to tell which is faster from this picture.

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The magnitude (size)of the energy of activation for the reverse reaction is exactly identical as it is for the forward reaction.

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The energy of activation may be affected by ________.


A) increasing the concentration of the reactants
B) higher temperature
C) decreasing the concentration of the reactants
D) the presence of a catalyst

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The reaction: HCl + NaOH → H2O + NaCl is a substitution reaction.

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Consider the reaction C → D with the following data: Energy of reactants = 30 kJ/mole; Energy of products = 20 kJ/mole; Energy of transition state = 60 kJ/mole. One can say with certainty that the reaction is ________ by ________kJ/mole and the energy of activation is ________ kJ/mole.


A) exothermic; 10; 30
B) endothermic; 10; 30
C) exothermic; 40; 30
D) endothermic; 40; 30

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The value of Ea(reaction)is equal to the difference Ea(reactants)- Ea(products).

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Industrial chemists often have their choice of catalysts to use when designing, for example, a factory that produces ammonia. Explain why biochemists studying life processes (such as protein metabolism)do not have the same variety of choices for which enzyme they would use.

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Enzymes are specifically designed, and s...

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A catalyst can be recovered at the end of the reaction.

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For chemical reactions to occur at all, "old" bonds must be broken and "new" bonds must form.

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Which of the following does not affect the rate of a reaction?


A) the concentration of the reactants
B) the energy of activation
C) the temperature
D) the pressure

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Consider the reaction A + B → C. Doubling the concentration of A leads to doubling the rate, while doubling the concentration of B quadruples the rate. The rate equation is, therefore, ________.


A) Rate = -k[A][B]2
B) Rate = -k[A]
C) Rate = - k[A]2
D) Rate = -k[A]2[B]

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A

A high energy of activation leads to more products favored in the reaction.

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Which of the following may be considered as biochemical catalysts?


A) carbohydrates
B) DNA
C) enzymes
D) lipids

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When the products are higher in energy than the reactants, the reaction is endothermic.

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Consider the reaction X → Y with the following data: Energy of reactants = 25 kJ/mole; Energy of products = 75 kJ/mole; Energy of transition state = 100 kJ/mole. The energy of activation for the reverse reaction is ________ kJ/mole.


A) 25
B) 50.
C) 75
D) 100

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In order for a chemical reaction to occur, ________.


A) the reactants must be in sufficient concentration
B) the products must be of lower energy than the reactants
C) the reactants must be of lower energy than the products
D) the reactants must possess sufficient energy to overcome the barrier of the activation energy

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