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The solubility of SrF2 in water (given Ksp = 2.6 × 10-9 ) is ________.


A) 4.3 × 10-4 M
B) 1.2 × 10-4 M
C) 7.6 × 10-5 M
D) 8.7 × 10-4 M

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For the reaction N2 (g) + 2H2 (g) ⇔ N2H4 (g) (endothermic) , what condition will increase the yield of product?


A) high temperature, high pressure
B) high temperature, low pressure
C) low temperature, high pressure
D) low temperature, low pressure

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For the following exothermic reaction: CO + 3H2 ⇔ CH3OH predict the direction of the reaction if: a)temperature is decreased (concentrations remain the same). b)a catalyst is added (concentrations AND temperature remain the same). c)the concentration of H2 is halved.

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a)a shift to the rig...

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Consider the equation: CH4 (g) + 2O2 (g) ⇔ CO2 (g) + 2H2O (g) to answer the questions below. -Refer to the equilibrium shown above. If the reaction vessel is expanded, this will ________.


A) shift the reaction to the right
B) shift the reaction to the left
C) have no effect
D) cannot be determined, since the temperature is unknown

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Write an expression for the equilibrium constant (Keq)for the following reactions -C6H5NH2 (aq)+ H2O (l)⇔ C6H5NH3+ (aq)+ OH- (aq)

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Keq = [C6H5NH3+]...

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Consider the equation 2NH3 (g) ⇔ N2 (g) + 3H2 (g) . Decreasing the concentration of ammonia gas will ________.


A) shift the reaction to the right
B) shift the reaction to the left
C) have no effect
D) cannot be determined, since the temperature is unknown

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In an exothermic reaction, adding heat will ________.


A) increase the amount of products
B) decrease the amount of reactants
C) decrease the amount of products
D) both A and B

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Consider the equation N2 (g) + 3H2 (g) ⇔ 2NH3 (g) . Removing ammonia as soon as it is formed will ________.


A) shift the reaction to the right
B) shift the reaction to the left
C) have no effect
D) cannot be determined, since the temperature is unknown

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Consider the reaction: 2H2S (g) + 3O2 (g) ⇔ 2SO2 (g) + 2H2O (g) to answer the following questions. -Refer to the reaction shown above. Adding H2O to the reaction vessel will ________.


A) shift the reaction to the right
B) shift the reaction to the left
C) have no effect
D) cannot be determined, since the temperature is unknown

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Consider the reaction: C (s)+ CO2 (g)⇔ 2 CO (g)(endothermic). Match each equilibrium change described in the questions with the corresponding consequence in the list below.

Premises
cooling the mixture
expanding the reaction vessel
adding heat
decreasing the pressure
adding extra carbon
adding extra carbon dioxide
adding carbon monoxide
increasing the pressure
Responses
Equilibrium is shifted to the left.
No effect on the equilibrium.
Equilibrium is shifted to the right.

Correct Answer

adding heat
Equilibrium is shifted to the right.
adding extra carbon
No effect on the equilibrium.
adding carbon monoxide
Equilibrium is shifted to the left.

The equilibrium constant is equal to which of the following?


A) kforward / kreverse
B) kreverse / kforward
C) kforward × kreverse
D) 1 / (kforward/kreverse)

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A

An equilibrium condition can be approached when the rate of a "forward" reaction slows down and the rate of a "reverse" reaction speeds up.

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In the reaction Cl2 (g)+ 3F2 (g)⇔ 2ClF3 (g), reducing the pressure will shift the equilibrium to the right.

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Identify each of the equilibrium constant values in the questions as "Equilibrium lies to the right/products favored" or "Equilibrium lies to the left/reactants favored".

Premises
2.3 × 103
3.7 × 103
4.5 × 10-2
2356.3
0.563
4.23
6.2 × 1010
3.1 × 10-8
Responses
Equilibrium lies to the right/ products favored
Equilibrium lies to the left/reactants favored

Correct Answer

2.3 × 103
3.7 × 103
4.5 × 10-2
2356.3
0.563
4.23
6.2 × 1010
3.1 × 10-8

A reaction that favors products has a Keq > 1.

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True

Consider the reaction: FeCl3 + KSCN ⇔ K3[Fe(SCN) 6] + 3KCl yellow colorless red colorless -Refer to the equilibrium shown above. Adding KSCN will ________.


A) turn the solution red.
B) turn the solution less red.
C) turn the solution clear.
D) have no effect on the color.

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If the solubility of copper(II) sulfate is 4.9 × 10-3 M, the solubility product is ________.


A) 2.4 × 10-5
B) 9.6 × 10-5
C) 1.2 × 10-2
D) 8.7 × 10-8

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Predict the effect of increasing pressure in each of the reactions in the questions by choosing the appropriate direction shift from the list below.

Premises
2 SO3 (g) + 2 Cl2 (g) ⇔ 2 SO2Cl2 (g) + O2 (g)
2 NH3 (g) ⇔ N2 (g) + 3 H2 (g)
2 C8H18 (g) + 25 O2 ⇔ 16 CO2 (g) + 18 H2O (g)
O2 (g) + 2F2 (g) ⇔ 2 OF2 (g)
l2 (g) + H2 (g) ⇔ 2 HI (g)
CH4 (g) + 2 O2 (g) ⇔ CO2 (g) + 2 H2O (g)
Responses
left (←)
no effect
right (→)

Correct Answer

2 SO3 (g) + 2 Cl2 (g) ⇔ 2 SO2Cl2 (g) + O2 (g)
2 NH3 (g) ⇔ N2 (g) + 3 H2 (g)
2 C8H18 (g) + 25 O2 ⇔ 16 CO2 (g) + 18 H2O (g)
O2 (g) + 2F2 (g) ⇔ 2 OF2 (g)
l2 (g) + H2 (g) ⇔ 2 HI (g)
CH4 (g) + 2 O2 (g) ⇔ CO2 (g) + 2 H2O (g)

In the reaction PCl5 ⇔ PCl3 + Cl2 at 500 K, the equilibrium concentrations of each species are [PCl5] = 0.008 M, [PCl3] = 0.02 M, and [Cl2] = 0.02 M. The equilibrium constant value is 0.5.

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If the value of the equilibrium constant for the forward reaction is 2.5 × 1030, the value of the equilibrium constant for the reverse reaction is 4.0 × 10-30.

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