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How much work is done by a person of mass 185 kg who climbs a ladder to the top of his house,a total of 15.0 m?


A) 2.78 kJ
B) 12.3 kJ
C) 27.2 kJ
D) No work is done.
E) 121 kJ

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If the standard enthalpy of combustion of octane,C8H18(l),at 298 K is -5471 kJ.mol-1 ,calculate the standard enthalpy of formation of octane.The standard enthalpies of formation of carbon dioxide and liquid water are -393.51 and -285.83 kJ.mol-1 ,respectively.

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-249 kJ.mo...

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What equation corresponds to the standard enthalpy of formation of gaseous hydrogen atoms,which,at 298 K is +217 kJ.mol-1 ?

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½H2

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The molar heat capacity of a monatomic ideal gas is independent of temperature and pressure.

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Calculate the enthalpy change that occurs when 1.00 kg of acetone condenses at its boiling point (329.4 K) .The standard enthalpy of vaporization of acetone is 29.1 kJ.mol-1.


A) (-502 kJ)
B) (-29.1 kJ)
C) (-2.91 * 104 kJ)
D) +502 kJ
E) +29.1 kJ

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Calculate the Br-Br bond enthalpy given the standard enthalpies of formation for Br2(g) and Br(g) ,30.7 and 112 kJ.mol-1 ,respectively.


A) 193 kJ.mol-1
B) 255 kJ.mol-1
C) 143 kJ.mol-1
D) 81 kJ.mol-1
E) 30.7 kJ.mol-1

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Calculate the lattice enthalpy of silver chloride from the following data. enthalpy of formation of Ag(g) : +284 kJ.mol-1 First ionization energy of Ag(g) : +731 kJ.mol-1 Enthalpy of formation of Cl(g) : +122 kJ.mol-1 Electron affinity of Cl(g) : +349 ( Δ\Delta H = kJ.mol-1 ) Enthalpy of formation of AgCl(s) : -127 kJ.mol-1


A) 1613 kJ.mol-1
B) 915 kJ.mol-1
C) 1037 kJ.mol-1
D) 1359 kJ.mol-1
E) 661 kJ.mol-1

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Calculate the lattice enthalpy of calcium oxide from the following data. enthalpy of formation of Ca(g) : +178 kJ.mol-1 First ionization energy of Ca(g) : +590 kJ.mol-1 Second ionization energy of Ca(g) : +1150 kJ.mol-1 Enthalpy of formation of O(g) : +249 kJ.mol-1 First electron affinity of O(g) : +141 ( Δ\Delta H = -141) kJ.mol-1 Second electron affinity of O(g) : -844 ( Δ\Delta H = +844) kJ.mol-1 Enthalpy of formation of CaO(s) : -635 kJ.mol-1


A) 1817 kJ.mol-1
B) 1391 kJ.mol-1
C) 2235 kJ.mol-1
D) 3754 kJ.mol-1
E) 3505 kJ.mol-1

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Calculate the lattice enthalpy of potassium fluoride from the following data. enthalpy of formation of K(g) : +89 kJ.mol-1 First ionization energy of K(g) : +418 kJ.mol-1 Enthalpy of formation of F(g) : +79 kJ.mol-1 Electron affinity of F(g) : +328 ( Δ\Delta H = -328) kJ.mol-1 Enthalpy of formation of KF(s) : -567 kJ.mol-1


A) 1481 kJ.mol-1
B) 825 kJ.mol-1
C) 904 kJ.mol-1
D) 497 kJ.mol-1
E) 347 kJ.mol-1

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Calculate the standard reaction enthalpy for the reaction. N2H4(l) + H2(g) \rightarrow 2NH3(g) Given: N2H4(l) + O2(g) \rightarrow N2(g) + 2H2O(g) Δ\Delta H° = -543 kJ.mol-1 2H2(g) + O2(g) \rightarrow 2H2O(g) Δ\Delta H° = -484 kJ.mol-1 N2(g) + 3H2(g) \rightarrow 2NH3(g) Δ\Delta H° = -92.2 kJ.mol-1


A) (-935 kJ.mol-1 )
B) (-1119 kJ.mol-1 )
C) (-151 kJ.mol-1 )
D) (-59 kJ.mol-1 )
E) (-243 kJ.mol-1 )

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What mass of ethanol,C2H5OH(l) ,must be burned to supply 500 kJ of heat? The standard enthalpy of combustion of ethanol at 298 K is -1368 kJ.mol-1


A) 126 g
B) 2.74 g
C) 16.8 g
D) 10.9 g
E) 29.7 g

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A reaction known to release 4.00 kJ of heat takes place in a calorimeter containing 0.200 L of solution and the temperature rose by 6.14 \circ C.When 200 mL of hydrochloric acid was added to a small piece of calcium carbonate in the same calorimeter,the temperature rose by 4.25 \circ C.What is the heat output for this reaction?


A) 0.0257 kJ-1.( \circ C) -1
B) 0.941 kJ-1.( \circ C) -1
C) 0.651 kJ-1.( \circ C) -1
D) 2.77 kJ-1.( \circ C) -1
E) 2.12 kJ-1.( \circ C) -1

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Calculate the standard reaction enthalpy for the following reaction. CH4(g) + H2O(g) \rightarrow CO(g) + 3H2(g) Given: 2H2(g) + CO(g) \rightarrow CH3OH(l) Δ\Delta H° = -128.3 kJ.mol-1 2CH4(g) + O2(g) \rightarrow 2CH3OH(l) Δ\Delta H° = -328.1 kJ.mol-1 2H2(g) + O2(g) \rightarrow 2H2O(g) Δ\Delta H° = -483.6 kJ.mol-1


A) +155.5 kJ.mol-1
B) + 216 kJ.mol-1
C) +412.1 kJ.mol-1
D) +42.0 kJ.mol-1
E) +206.1 kJ.mol-1

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When nitrogen gas expands from 3.00 to 6.00 L and 2.00 kJ of energy is transferred as heat to the nitrogen in a cylinder fitted with a piston at an external pressure of 2.00 atm,against this constant pressure,what is Δ\Delta U for the process?


A) (-0.608 kJ)
B) +2.61 kJ
C) (-2.61 kJ)
D) 0
E) +1.39 kJ

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The combustion of 1 mole of octane,C8H18(l) ,to produce carbon dioxide and liquid water has Δ\Delta Hr = -5471 kJ.mol-1 at 298 K.What is the change in internal energy for this reaction?


A) (-5460 kJ.mol-1 )
B) (-5482 kJ.mol-1 )
C) (-5449 kJ.mol-1 )
D) (-5471 kJ.mol-1 )
E) (-5493 kJ.mol-1 )

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How much heat is required to vaporize 50.0 g of water if the initial temperature of the water is 25.0 \circ C and the water is heated to its boiling point,where it is converted to steam? The specific heat capacity of water is 4.18 J.( \circ C) -1.g-1 and the standard enthalpy of vaporization of water at its boiling point is 40.7 kJ.mol-1.


A) 169 kJ
B) 64.2 kJ
C) 40.7 kJ
D) 193 kJ
E) 23.5 kJ

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Use the following information to determine the standard enthalpy of formation of NH3(g) . N-H bond enthalpy = 390 kJ.mol-1 Δ\Delta Hf \circ (H(g) ) = 217.9 kJ.mol-1 Δ\Delta Hf \circ (N(g) ) = 472.6 kJ.mol-1


A) (-44 kJ.mol-1 )
B) (-691 kJ.mol-1 )
C) (-516 kJ.mol-1 )
D) (-83 kJ.mol-1 )
E) (-1170 kJ.mol-1 )

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Calculate the enthalpy change that occurs when 1 lb (454 G) of mercury freezes at its freezing point (234.3 K) .The standard enthalpy of fusion of mercury is 2.29 kJ.mol-1.


A) (-2.29 kJ )
B) (-1.04 * 103 kJ)
C) +5.18 kJ
D) +2.29 kJ
E) -5.18 kJ

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A piece of a newly synthesized material of mass 12.0 g at 88.0 \circ C is placed in a calorimeter containing 100.0 g of water at 20.0 \circ C.If the final temperature of the system is 24.0 \circ C,what is the specific heat capacity of this material?


A) 10.2 J.g-1.( \circ C) -1
B) 1.58 J.g-1.( \circ C) -1
C) 2.18 J.g-1.( \circ C) -1
D) 9.50 J.g-1.( \circ C) -1
E) 0.54 J.g-1.( \circ C) -1

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Combustion reactions can be exothermic or endothermic.

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