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Which of the following compounds exhibits hydrogen bonding?


A) CH3Br
B) HCl
C) CH3SCH3
D) CH3OH

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Explain why ice floats in water.


A) Ice is more dense than water.
B) Steam is less dense than water.
C) Ice is less dense than water.
D) Steam is more dense than water.
E) Ice is the same density as water.

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Define dynamic equilibrium.

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Dynamic equilibrium ...

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Identify the compound that does NOT have dipole-dipole forces as its strongest force.


A) CH2I2
B) CH3OCH3
C) CH3Cl
D) HCBr3
E) CO2

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Ethyl chloride,C2H5Cl,is used as a local anesthetic.It works by cooling tissue as it vaporizes; its heat of vaporization is 26.4 kJ/mol.How much heat could be removed by 10.0 g of ethyl chloride?


A) 4.09 kJ
B) 170 kJ
C) 264 kJ
D) 1700 kJ

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Define fusion.


A) the phase transition from solid to liquid
B) the phase transition from gas to solid
C) the phase transition from gas to liquid
D) the phase transition from liquid to gas
E) the phase transition from liquid to solid

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How much energy is required to vaporize 98.6 g of ethanol (C2H5OH) at its boiling point,if its ΔHvap is 40.5 kJ/mol?


A) 86.7 kJ
B) 11.5 kJ
C) 18.9 kJ
D) 52.8 kJ
E) 39.9 kJ

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Describe sweating in humans.


A) It is an endothermic reaction.
B) The sweat evaporates absorbing heat from the body.
C) The skin is cooled.
D) None of the above
E) All of the above

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The forces between polar molecules are known as


A) hydrogen bonding.
B) ion-dipole forces.
C) dipole-dipole forces.
D) dispersion forces.
E) ionic forces.

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Determine ΔHvap for a compound that has a measured vapor pressure of 24.3 torr at 273 K and 135 torr at 325 K.


A) 41 kJ/mol
B) 79 kJ/mol
C) 24 kJ/mol
D) 13 kJ/mol
E) 34 kJ/mol

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Choose the molecule or compound that exhibits dispersion forces as its strongest intermolecular force.


A) Cl2
B) CO
C) HBr
D) NaCl
E) All of these have intermolecular forces stronger than dispersion.

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Place the following substances in order of decreasing boiling point. He Ar H2


A) He > H2 > Ar
B) H2 > He > Ar
C) He > Ar > H2
D) Ar > He > H2
E) H2 > Ar > He

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Identify the compound that does NOT have hydrogen bonding.


A) (CH3) 2N(CH2) 3CH3
B) H2O
C) CH3(CH2) 5
D) HF
E) CH3(CH2) 2NH2

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Place the following substances in order of increasing boiling point. He I2 O2


A) He < I2 < O2
B) I2 < O2 < He
C) O2 < I2 < He
D) I2 < He < O2
E) He < O2 < I2

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How many compounds,of the ones listed below,have hydrogen bonding? CH3(CH2) 2NH2 CH3(CH2) 2NH(CH2) 4CH3 (CH3CH2) 2N(CH2) 4CH3


A) 2
B) 3
C) 1
D) 0

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Place the following substances in order of decreasing vapor pressure at a given temperature. BeF2 CH3OH OF2


A) CH3OH > OF2 > BeF2
B) BeF2 > OF2 > CH3OH
C) OF2 > CH3OH > BeF2
D) OF2 > BeF2 > CH3OH
E) BeF2 > CH3OH > OF2

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Define deposition.


A) A liquid becomes a gas.
B) A gas becomes a liquid.
C) A gas becomes a solid.
D) A solid becomes a gas.
E) A solid becomes a liquid.

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Identify the place which has the highest boiling point of water.


A) Death Valley, 282 feet below sea level
B) A pressurized passenger jet, 39,000 feet
C) Panama City, Florida, sea level
D) Mt. Everest, 29,035 feet
E) Denver, Colorado, 5,280 feet

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Which of the following statements is FALSE?


A) The rate of vaporization increases with increasing surface area.
B) The rate of vaporization increases with decreasing strength of intermolecular forces.
C) The rate of vaporization increases with increasing temperature.
D) Molecules with hydrogen bonding are more volatile than compounds with dipole-dipole forces.
E) None of the above is false.

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The melting point of water is ________.


A) 0°C
B) 32 K
C) 212°C
D) 100°F
E) 273°F

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