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If a strong acid such as HCl is diluted sufficiently with water,the pH will be higher than 7.

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What is the pH of a 0.050 M HBr solution?


A) 0.89
B) 1.12
C) 1.30
D) 3.00
E) None of these choices is correct.

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A solution of sodium acetate (CH3COONa)in water is weakly basic.

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A solution is prepared by adding 0.10 mol of sodium sulfide,Na2S,to 1.00 L of water.Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentration of sodium ions and sulfide ions will be identical.
E) The concentration of sulfide ions will be greater than the concentration of sodium ions.

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What is the [H3O+] for a solution at 25°C that has pOH = 5.640?


A) 2.34 ×\times 10-4 M
B) 2.29 ×\times 10-6 M
C) 4.37 ×\times 10-9 M
D) 4.27 ×\times 10-11 M
E) 8.360 M

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A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution.The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants.Which of the statements about the equilibrium system is correct? H2C2O4(aq) + H2PO4-(aq) A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution.The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants.Which of the statements about the equilibrium system is correct? H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>(aq) + H<sub>2</sub>PO<sub>4</sub><sup>-</sup>(aq)    HC<sub>2</sub>O<sub>4</sub><sup>-</sup>(aq) + H<sub>3</sub>PO<sub>4</sub>(aq)  A) Oxalic acid is a weaker acid than phosphoric acid. B) The hydrogen oxalate anion,HC<sub>2</sub>O<sub>4</sub><sup>-</sup>,is a stronger base than the dihydrogen phosphate anion,H<sub>2</sub>PO<sub>4</sub><sup>-</sup>. C) Phosphoric acid is a weaker acid than oxalic acid. D) The dihydrogen phosphate anion,H<sub>2</sub>PO<sub>4</sub><sup>-</sup>,is a stronger acid than oxalic acid. E) Water is a stronger acid than either oxalic or phosphoric acids. HC2O4-(aq) + H3PO4(aq)


A) Oxalic acid is a weaker acid than phosphoric acid.
B) The hydrogen oxalate anion,HC2O4-,is a stronger base than the dihydrogen phosphate anion,H2PO4-.
C) Phosphoric acid is a weaker acid than oxalic acid.
D) The dihydrogen phosphate anion,H2PO4-,is a stronger acid than oxalic acid.
E) Water is a stronger acid than either oxalic or phosphoric acids.

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Which one of the following substances will give an aqueous solution of pH < 7?


A) KI
B) NH4Br
C) Na2CO3
D) CH3COONa
E) CH3OH

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What is the value of Kb for the cyanide anion,CN-? Ka(HCN) = 6.2 ×\times 10-10


A) 1.6 ×\times 10-4
B) 1.6 ×\times 10-5
C) 3.8 ×\times 10-4
D) 3.8 ×\times 10-5
E) 6.2 ×\times 104

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A 0.15 M solution of chloroacetic acid has a pH of 1.86.What is the value of Ka for this acid?


A) 7.2 ×\times 101
B) 0.16
C) 0.099
D) 0.0014
E) 0.00027

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According to Brønsted and Lowry,which one of the following is not a conjugate acid-base pair?


A) H3O+/OH-
B) CH3OH2+/CH3OH
C) HI/I-
D) HSO4-/SO42-
E) H2/H-

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All weak acids have strong conjugate bases.

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Which of the following pairs has the stronger acid listed first?


A) HBr,HI
B) HClO2,HClO3
C) H2SeO4,H2SeO3
D) HNO2,HNO3
E) HF,HCl

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What is the pH of a 0.0100 M sodium benzoate solution? Kb (C7H5O2-) = 1.5 ×\times 10-10


A) 0.38
B) 5.91
C) 8.09
D) 9.82
E) 13.62

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Farmers who raise cotton once used arsenic acid,H3AsO4,as a defoliant at harvest time.Arsenic acid is a polyprotic acid with K1 = 2.5 ×\times 10-4,K2 = 5.6 ×\times 10-8,and K3 = 3 ×\times 10-13.What is the pH of a 0.500 M solution of arsenic acid?


A) 0.85
B) 1.96
C) 3.90
D) 4.51
E) None of these choices is correct.

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Formic acid,which is a component of insect venom,has a Ka = 1.8 ×\times 10-4.What is the [H3O+] in a solution that is initially 0.10 M formic acid,HCOOH?


A) 4.2 ×\times 10-3 M
B) 8.4 ×\times 10-3 M
C) 1.8 ×\times 10-4 M
D) 1.8 ×\times 10-5 M
E) 1.8 ×\times 10-6 M

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What is the pH of a 0.010 M triethanolammonium chloride, (HOC2H2) 3NHCl,solution? Kb, ((HOC2H2) 3N) = 5.9 ×\times 10-7


A) 2.75
B) 4.89
C) 9.11
D) 11.25
E) None of these choices is correct.

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What is the pH of a 0.20 M HCl solution?


A) < 0
B) 0.70
C) 1.61
D) 12.39
E) 13.30

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A 0.050 M solution of the weak acid HA has [H3O+] = 3.77 ×\times 10-4 M.What is the Ka for the acid?


A) 7.5 ×\times 10-3 M
B) 2.8 ×\times 10-6 M
C) 7.0 ×\times 10-7 M
D) 7.0 ×\times 10-8 M
E) 2.6 ×\times 10-11 M

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Arsenic acid,H3AsO4,is used industrially to manufacture insecticides.Arsenic acid is a polyprotic acid with K1 = 2.5 ×\times 10-4,K2 = 5.6 ×\times 10-8,and K3 = 3 ×\times 10-13.What is the concentration of the HAsO42- in a solution whose initial arsenic acid concentration was 0.35 M?


A) 9.4 ×\times 10-3 M
B) 2.5 ×\times 10-4 M
C) 8.8 ×\times 10-5 M
D) 5.6 ×\times 10-8 M
E) None of these choices is correct.

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The substance H2SO3 is considered


A) a weak Arrhenius base.
B) a strong Arrhenius acid.
C) a strong Arrhenius base.
D) a neutral compound.
E) a weak Arrhenius acid.

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