A)
B)
C)
D)
E) More than one of the above
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Essay
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B)
C)
D)
E)
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E)
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Multiple Choice
A) Protonation of the alcohol is a fast step.
B) Formation of a carbocation from the protonated alcohol is a slow step.
C) Rearrangements of less stable carbocations to more stable carbocations are common.
D) Loss of a proton by the carbocation is a fast step.
E) All of the above
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A)
B)
C)
D)
E) None of the above
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Multiple Choice
A) 3,3,5-trimethyl-2-hexene
B) 3-isobutyl-3-isopropyl-2-propene
C) 3-isobutyl-4-methyl-2-pentene
D) 3-(1-methylethyl) -5-methyl-2-hexene
E) None of the above
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B)
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E)
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A) (E) -2-Bromo-3-chloro-5-methyl-2-hexene
B) (E) -2-Bromo-3-chloro-5-methyl-3-hexene
C) (Z) -2-Bromo-3-chloro-5-methyl-3-hexene
D) (Z) -2-Bromo-3-chloro-5-methyl-2-hexene
E) (E) -2-Methyl-5-bromo-4-chloro-4-hexene
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A)
B)
C)
D)
E)
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Multiple Choice
A) rearrange to a more stable carbocation.
B) lose a proton to form an alkene.
C) combine with a nucleophile.
D) react with an alkene to form a larger carbocation.
E) do all of the above.
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A)
B)
C)
D)
E) More than one of the above
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Multiple Choice
A) They do not alkylate with secondary alkyl halides.
B) Primary alkyl halides are best suited for alkylation.
C) In the presence of tertiary alkyl halides,the acetylide anion acts as base to give an elimination product.
D) Only two of the above are true.
E) All of the statements are true.
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Essay
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B)
C)
D)
E)
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Multiple Choice
A) Unless hydrogenation of the alkenes gives the same alkane,heats of hydrogenation cannot be used to measure their relative stabilities.
B) In general,the greater the number of alkyl groups attached to the carbon atoms of the double bond,the greater the stability of the alkene.
C) The greater the quantity of heat liberated on combustion or hydrogenation of an alkene,the greater its energy content.
D) trans-Cycloalkenes are always more stable than the cis-isomers.
E) Heats of combustion can be used to measure the relative stabilities of isomeric alkenes,even though their hydrogenation products are not identical.
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B)
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E)
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