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When proton transfer reactions reach equilibrium,there have been formed


A) the weaker acid and the weaker base.
B) the weaker acid and the stronger base.
C) the stronger acid and the weaker base.
D) the stronger acid and the stronger base.
E) All proton transfers go to completion; they are not equilibrium processes.

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The correct sequence of the ions shown,in order of increasing basicity,is:


A) CH3CH2:- < CH2=CH:- < HC \equiv C:-
B) CH3CH2:- < HC \equiv C:- < CH2=CH:-
C) HC \equiv C:- < CH3CH2:- < CH2=CH:-
D) CH2=CH:- < HC \equiv C:- < CH3CH2:-
E) HC \equiv C:- < CH2=CH:- < CH3CH2:-

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Which set contains non-equivalent members?


A) enthalpy and heat content
B) endothermic reaction and + Δ\Delta H
C) exothermic reaction and - Δ\Delta H
D) kinetic energy and energy of motion
E) high energy and high stability

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Which acid-base reaction would not take place as written?


A) CH3Li + CH3CH2OH \to CH4 + CH3CH2OLi
B) HC \equiv CH + NaOH \to HC \equiv CNa + H2O
C) HC \equiv CNa + H2O \to HC \equiv CH + NaOH
D) CH3OH + NaH \to CH3ONa + H2
E) CH3CO2H + CH3ONa \to CH3CO2Na + CH3OH

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Rank the bold-faced hydrogens for the following compounds from most acidic to least acidic. Rank the bold-faced hydrogens for the following compounds from most acidic to least acidic.   A) I > IV > II > V > III B) II > IV > I > V > III C) II > IV > V > I > III D) IV > I > II > V > III E) IV > II > I > V > III


A) I > IV > II > V > III
B) II > IV > I > V > III
C) II > IV > V > I > III
D) IV > I > II > V > III
E) IV > II > I > V > III

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You are planning to purify an impure sample of benzoic acid,known to be contaminated with naphthalene.Propose a strategy for purifying this sample,making use of acid-base principles,using equations to further clarify your answer.

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Benzoic acid reacts with aqueous NaOH to...

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Which of the following organic compounds is the strongest acid?


A) C6H12 pKa = 52
B) CH3CH3 pKa = 50
C) CH3CH2OH pKa = 18
D) CH3CO2H pKa = 5
E) CF3CO2H pKa = 0

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Isotope labeling is an important tool in the study of reaction mechanisms.How will you selectively deuterate the specified hydrogen atom,indicated by an arrow,in the following compound? Use equations to clarify your answer and briefly explain your rationale. Isotope labeling is an important tool in the study of reaction mechanisms.How will you selectively deuterate the specified hydrogen atom,indicated by an arrow,in the following compound? Use equations to clarify your answer and briefly explain your rationale.

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The specified hydrogen is attached to an...

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For the following acid / base reaction which statement is true taking Δ\Delta H into consideration?  For the following acid / base reaction which statement is true taking  \Delta H into consideration?   A) The reaction is an exothermic reaction and  \Delta H is approximately zero. B) The reaction is an endothermic reaction and  \Delta H is negative. C) The reaction is an exothermic reaction and  \Delta H is negative. D) The reaction is an exothermic reaction and  \Delta H is positive. E) None of these choices.


A) The reaction is an exothermic reaction and Δ\Delta H is approximately zero.
B) The reaction is an endothermic reaction and Δ\Delta H is negative.
C) The reaction is an exothermic reaction and Δ\Delta H is negative.
D) The reaction is an exothermic reaction and Δ\Delta H is positive.
E) None of these choices.

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