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Nitric oxide, an important pollutant in air, is formed from the elements nitrogen and oxygen at high temperatures, such as those obtained when gasoline burns in an automobile engine. At 2000°C, K for the reaction N2(g) + O2(g) Nitric oxide, an important pollutant in air, is formed from the elements nitrogen and oxygen at high temperatures, such as those obtained when gasoline burns in an automobile engine. At 2000°C, K for the reaction N<sub>2</sub>(g)  + O<sub>2</sub>(g)    2NO(g)  is 0.01. Predict the direction in which the system will move to reach equilibrium at 2000°C if 0.4 mol of N<sub>2</sub>, 0.1 mol of O<sub>2</sub>, and 0.08 mol of NO are placed in a 1.0-L container. A)  The system remains unchanged. B)  The concentration of NO will decrease; the concentrations of N<sub>2</sub> and O<sub>2</sub> will remain unchanged. C)  The concentration of NO will decrease; the concentrations of N<sub>2</sub> and O<sub>2</sub> will increase. D)  The concentration of NO will increase; the concentrations of N<sub>2</sub> and O<sub>2</sub> will decrease. E)  More information is necessary. 2NO(g) is 0.01. Predict the direction in which the system will move to reach equilibrium at 2000°C if 0.4 mol of N2, 0.1 mol of O2, and 0.08 mol of NO are placed in a 1.0-L container.


A) The system remains unchanged.
B) The concentration of NO will decrease; the concentrations of N2 and O2 will remain unchanged.
C) The concentration of NO will decrease; the concentrations of N2 and O2 will increase.
D) The concentration of NO will increase; the concentrations of N2 and O2 will decrease.
E) More information is necessary.

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At a certain temperature, K for the reaction 2NO2 At a certain temperature, K for the reaction 2NO<sub>2</sub>   N<sub>2</sub>O<sub>4</sub> Is 7.5 L/mol. If 2.0 mol of NO<sub>2</sub> is placed in a 2.0-liter container and permitted to react at this temperature, calculate the concentration of N<sub>2</sub>O<sub>4</sub> at equilibrium. A)  0.39 mol/L B)  0.82 mol/L C)  7.5 mol/L D)  0.65 mol/L E)  none of these N2O4 Is 7.5 L/mol. If 2.0 mol of NO2 is placed in a 2.0-liter container and permitted to react at this temperature, calculate the concentration of N2O4 at equilibrium.


A) 0.39 mol/L
B) 0.82 mol/L
C) 7.5 mol/L
D) 0.65 mol/L
E) none of these

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What is the value of Q0, the reaction quotient, based on the conditions above?


A) 0.50
B) 0.125
C) 4.00
D) 1.00
E) None of the above

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Once equilibrium was established, some additional chlorine gas was added to the system. This resulted in


A) no net change in the amounts of the other reaction components.
B) an increase in the amount of H2O relative to the equilibrium mixture.
C) a decrease in the amount of H2O relative to the equilibrium mixture.
D) a decrease in the amount of HCl relative to the equilibrium mixture.
E) both B and D

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To achieve equilibrium, the original reaction mixture will


A) produce more water and oxygen only
B) experience no change in component pressures
C) always move in a direction to lower the total pressure
D) shift toward products
E) shift toward reactants

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Which of the following statements concerning equilibrium is not true?


A) A system that is disturbed from an equilibrium condition responds in such a way as to restore equilibrium.
B) The value of the equilibrium constant for a given reaction mixture is the same regardless of the direction from which equilibrium is attained.
C) Equilibrium in molecular systems is dynamic, with two opposing processes balancing one another.
D) The equilibrium constant is independent of temperature.
E) A system moves spontaneously toward a state of equilibrium.

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At a given temperature, the equilibrium constant K for the reaction 2SO2(g) + O2(g) At a given temperature, the equilibrium constant K for the reaction 2SO<sub>2</sub>(g)  + O<sub>2</sub>(g)    2SO<sub>3</sub>(g)  Is 3.0 <font face= symbol ></font> 10<sup>9</sup>. If 2.60 mol of SO<sub>2</sub> and 3.90 mol of O<sub>2</sub> are placed in a 1.78-L container and allowed to react to equilibrium at this temperature, what is the concentration of SO<sub>3</sub> at equilibrium? A)  1.46 M B)  0.730 M C)  2.92 M D)  3.65 M E)  2.19 M 2SO3(g) Is 3.0 109. If 2.60 mol of SO2 and 3.90 mol of O2 are placed in a 1.78-L container and allowed to react to equilibrium at this temperature, what is the concentration of SO3 at equilibrium?


A) 1.46 M
B) 0.730 M
C) 2.92 M
D) 3.65 M
E) 2.19 M

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The equilibrium constant for A + 2B The equilibrium constant for A + 2B   3C is 1.0 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup>. Determine the equilibrium constant for 4A + 8B   12C. A)  1.0 <font face= symbol ></font> 10<sup>-</sup><sup>24</sup> B)  1.0 <font face= symbol ></font> 10<sup>24</sup> C)  1.0 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup> D)  4 <font face= symbol ></font> 10<sup>-</sup><sup>24</sup> E)  4 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup> 3C is 1.0 10-6. Determine the equilibrium constant for 4A + 8B The equilibrium constant for A + 2B   3C is 1.0 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup>. Determine the equilibrium constant for 4A + 8B   12C. A)  1.0 <font face= symbol ></font> 10<sup>-</sup><sup>24</sup> B)  1.0 <font face= symbol ></font> 10<sup>24</sup> C)  1.0 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup> D)  4 <font face= symbol ></font> 10<sup>-</sup><sup>24</sup> E)  4 <font face= symbol ></font> 10<sup>-</sup><sup>6</sup> 12C.


A) 1.0 10-24
B) 1.0 1024
C) 1.0 10-6
D) 4 10-24
E) 4 10-6

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A sample of solid NH4NO3 was placed in an evacuated container and then heated so that it decomposed explosively according to the following reaction: NH4NO3(s) A sample of solid NH<sub>4</sub>NO<sub>3</sub> was placed in an evacuated container and then heated so that it decomposed explosively according to the following reaction: NH<sub>4</sub>NO<sub>3</sub>(s)    N<sub>2</sub>O(g)  + 2H<sub>2</sub>O(g)  At equilibrium, the total pressure in the container was found to be 2.25 atm at a temperature of 500°C. Calculate K<sub>p</sub>. A)  2.25. B)  5.06 C)  45.6 D)  1.69 E)  2.25 N2O(g) + 2H2O(g) At equilibrium, the total pressure in the container was found to be 2.25 atm at a temperature of 500°C. Calculate Kp.


A) 2.25.
B) 5.06
C) 45.6
D) 1.69
E) 2.25

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The reaction H2(g) + I2(g) The reaction H<sub>2</sub>(g)  + I<sub>2</sub>(g)    2HI(g)  Has K<sub>p</sub> = 45.9 at 763 K. A particular equilibrium mixture at that temperature contains gaseous HI at a partial pressure of 4.30 atm and hydrogen gas at a partial pressure of 0.225 atm. What is the partial pressure of I<sub>2</sub>? A)  1.79 atm B)  0.225 atm C)  0.833 atm D)  37.1 atm E)  0.416 atm 2HI(g) Has Kp = 45.9 at 763 K. A particular equilibrium mixture at that temperature contains gaseous HI at a partial pressure of 4.30 atm and hydrogen gas at a partial pressure of 0.225 atm. What is the partial pressure of I2?


A) 1.79 atm
B) 0.225 atm
C) 0.833 atm
D) 37.1 atm
E) 0.416 atm

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Consider the following reaction, which is involved in the catalytic destruction of ozone by chlorine atoms. ClO(g) + O3(g) Consider the following reaction, which is involved in the catalytic destruction of ozone by chlorine atoms. ClO(g) + O<sub>3</sub>(g)   Cl(g) + 2O<sub>2</sub>(g) K<sub>p</sub> = 2.5 * 10<sup>6</sup> atm at 25° C. In an experiment at 25° C, ClO(g) at 1.0 *10<sup>-</sup><sup>3</sup> atm was mixed with O<sub>3</sub>(g) at 2.0 *10<sup>-</sup><sup>5</sup> atm in a rigid vessel. Calculate the equilibrium pressure of O<sub>3</sub>(g) and O<sub>2</sub>(g). Cl(g) + 2O2(g) Kp = 2.5 * 106 atm at 25° C. In an experiment at 25° C, ClO(g) at 1.0 *10-3 atm was mixed with O3(g) at 2.0 *10-5 atm in a rigid vessel. Calculate the equilibrium pressure of O3(g) and O2(g).

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For O3, 1.3 *10

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